Third law of thermodynamics

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The Third law of thermodynamics says:

The statement is: At absolute zero, the entropy of a perfectly crystalline substance is zero.

Experimentally,it is not possible to obtain -273.15°C.It is found that most of the gases either liquified or solidified before reaching such a lower temperature and gases molecules(always exist as polyatomic molecule-Avagadro's law)does not remain.

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