Lead

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Sn

Pb

Fl
Appearance
metallic gray
General properties
Name, symbol, number lead, Pb, 82
Pronunciation /ˈlɛd/ LED
Element category post-transition metal
Group, period, block 146, p
Standard atomic weight 207.2 g·mol−1
Electron configuration [Xe] 4f14 5d10 6s2 6p2
Electrons per shell 2, 8, 18, 32, 18, 4 (Image)
Physical properties
Phase solid
Density (near r.t.) 11.34 g·cm−3
Liquid density at m.p. 10.66 g·cm−3
Melting point 600.61 K, 327.46 °C, 621.43 °F
Boiling point 2022 K, 1749 °C, 3180 °F
Heat of fusion 4.77 kJ·mol−1
Heat of vaporization 179.5 kJ·mol−1
Specific heat capacity (25 °C) 26.650 J·mol−1·K−1
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 978 1088 1229 1412 1660 2027
Atomic properties
Oxidation states 4, 3, 2, 1

(Amphoteric oxide)

Electronegativity 2.33 (Pauling scale)
Ionization energies 1st: 715.6 kJ·mol−1
2nd: 1450.5 kJ·mol−1
3rd: 3081.5 kJ·mol−1
Atomic radius 175 pm
Covalent radius 146±5 pm
Van der Waals radius 202 pm
Miscellanea
Crystal structure face-centered cubic
Magnetic ordering diamagnetic
Electrical resistivity (20 °C) 208 nΩ·m
Thermal conductivity (300 K) 35.3 W·m−1·K−1
Thermal expansion (25 °C) 28.9 µm·m−1·K−1
Speed of sound (thin rod) (r.t.) (annealed)
1190 m·s−1
Young's modulus 16 GPa
Shear modulus 5.6 GPa
Bulk modulus 46 GPa
Poisson ratio 0.44
Mohs hardness 1.5
Brinell hardness 38.3 MPa
CAS registry number 7439-92-1
Most stable isotopes
Main article: Isotopes of lead
iso NA half-life DM DE (MeV) DP
204Pb 1.4% >1.4×1017 y α 1.972 200Hg
205Pb syn 1.53×107 y ε 0.051 205Tl
206Pb 24.1% 206Pb is stable with 124 neutrons
207Pb 22.1% 207Pb is stable with 125 neutrons
208Pb 52.4% >2×1019 y α 0.5188 204Hg
210Pb trace 22.3 y α 3.792 206Hg
β 0.064 210Bi
Lead

Lead (pronounce: "lehd") is a chemical element. Its chemical symbol is Pb, which comes from plumbum, the Latin word for lead.[1] Its atomic number is 82, atomic mass is 207.2 and has a melting point of 327.8°C. It is a very poisonous and heavy metal.

Properties[change | edit source]

Physical properties[change | edit source]

Lead powder burning

Lead is a shiny, gray-blue poor metal. It gets tarnished easily to a dull gray color. It is soft and malleable. It is very shiny when it is melted. It is very heavy. It is very corrosion-resistant. It is made stronger by adding antimony or calcium. It can form an alloy with sodium. It is toxic to people and animals when swallowed.

Chemical properties[change | edit source]

Flame test for lead

Lead burns in air with a grayish-white flame, making toxic fumes of lead(II) oxide. Only the surface is corroded by air. It dissolves in nitric acid to make lead(II) nitrate. It does not dissolve in sulfuric or hydrochloric acid. It reacts with sodium nitrate to make lead(II) oxide and sodium nitrite. It reacts with chlorine to make lead(II) chloride. Lead(II) oxide reacts with lead sulfide to make lead metal and sulfur dioxide.

Chemical compounds[change | edit source]

Lead makes chemical compounds in two main oxidation states: +2 and +4. +2 compounds, also known as lead(II) compounds or plumbous compounds, are weak oxidizing agents. +4 compounds, also known as lead(IV) compounds or plumbic compounds, are strong oxidizing agents. Lead compounds are toxic just like the element. The lead halides do not dissolve in water. Lead(IV) oxide is the most common lead(IV) compound. It is a black solid. The lead oxides are all colored, while the other salts are white or colorless. Lead nitrate and lead(II) acetate are the soluble compounds of lead.

+2 compounds

This state is more common than the +4 state. These are weak oxidizing agents. All but the oxides are colorless or white.

Mixed oxidation state compounds

Mixed oxidation state compounds contain lead in the +2 and +4 oxidation state.

+4 compounds

These are less common. They are strong oxidizing agents.

Occurrence[change | edit source]

Lead is found very rarely in the earth's crust as a metal. Normally, lead is in the mineral galena. Galena is lead sulfide. Galena is the main lead ore.

History[change | edit source]

Lead was used for thousands of years because it is easy to get from the ground and easy to shape and work with. The Romans used lead very commonly. They used it for pipes, drinking vessels, and fasteners.

Preparation[change | edit source]

Lead is made from galena. Galena is made pure by froth flotation to get all the impurities out. Then the lead sulfide is roasted in a furnace to make lead(II) oxide. The lead(II) oxide is heated with coke to make liquid lead metal.

Uses[change | edit source]

As an element[change | edit source]

The dark bricks are made of lead. They are meant to keep people safe from the radioactive material inside.

Lead is used in the ballast of sailboats. It is also used in weight belts for scuba diving. It is also used to make shotgun pellets and bullets for small arms. Some printing presses use lead type because it can be easily shaped. It can be used outside because it does not corrode in water.

Most lead is used in lead acid batteries, though. The lead is oxidized, making electricity. Sheets of lead are used to block sound in some places. Lead is used in radiation shielding. Molten lead can be used as a coolant in nuclear reactors. It used to be mixed with tin to make the pipes in pipe organs. Different amounts of lead make different sounds. In addition, lead has found its usage in solder.

It is used in some solder. It is used in covering for wires that carry high voltage. Some tennis rackets have lead in them to make them heavier. It is used to balance wheels of cars, to make statues, and to make decorative looks in buildings.

As chemical compounds[change | edit source]

Many lead compounds are used to make colored glazes in ceramics. Lead can be used in PVC pipes. Lead compounds are added to candles to make them burn better. Lead glass has lead(II) oxide in it. Lead compounds are still used as pigments in some places. Lead compounds were added to gasoline, but are now outlawed. Some lead compounds are semiconductors and are used in photodetectors.

Old uses[change | edit source]

Lead was used in many red, yellow, and white pigments in paints. Lead was also used in pesticides. Lead used to be used in pipes carrying water, but now it is not because lead can leach into the water.

Safety[change | edit source]

Although it can be safely touched, exposure to lead should be avoided – it is very toxic to humans and other animals when swallowed, and its use is restricted in many countries.

If someone is exposed to lead for a long time, it ruins their kidneys and gives them abdominal pains. Lead also ruins the nervous system. Lead paint was being eaten by children and they were getting lead poisoning.

The best way to understand lead and its properties is to read its MSDS.

Other pages[change | edit source]

References[change | edit source]