File:DSC01973 - Nickel (II) reactions.JPG
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Summary
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English: Reactions of Nickel(II)-nitrate. From left to right:
Pure solution of Nickel(II)-nitrate. You still can see the green color. With (NH4)2S: Ni2+ + S2- -> NiS(s) (The black precipitation is first soluble in acid. After corrosion with air oxygen over Ni(OH)S to Ni2S3, the end product is persistent to acid.) With NaOH: Ni2+ + 2OH- -> Ni(OH)2(s). (Beautiful light green huge flakes. Hardly soluble in OH- surplus.) With NH3: Ni(NO3)2 + 2OH- + 2NH4+ -> Ni(OH)2 + 2NaNO3 Ni(OH)2 + 6NH3 -> [Ni(NH3)6]2+ + 2OH- (The hydroxide dissolves to the blue complex solution very quickly.) With Na2CO3: Ni2+ + CO2- -> green alkaline Carbonate salts of varying composition.Deutsch: Reaktionen mit Nickel(II)nitrat. Von links nach rechts:
Reine Lösungvon Nickel(II)nitrat. Die grüne Farbe der Lösung ist auch in dieser geringen Konzentration noch gut erkennbar. Mit (NH4)2S: Ni2+ + S2- -> NiS(s) (Zunächst ist der frisch gefällte schwarze Niederschlag noch säurelöslich. Nach einem Alterungsprozess mit Luftsauerstoff über Ni(OH)S zu Ni2S3 ist das Endprodukt aber beständig gegen Säuren.) Mit NaOH: Ni2+ + 2OH- -> Ni(OH)2(s). (Schöne hellgrüne, große Flocken. Im Überschuss kaum löslich.) Mit NH3: Ni(NO3)2 + 2OH- + 2NH4+ -> Ni(OH)2 + 2NaNO3 Ni(OH)2 + 6NH3 -> [Ni(NH3)6]2+ + 2OH- (Hiermit löst sich das Hydroxid schon in geringem Überschuss zu einer blauen Komplexlösung.) Mit Na2CO3: Ni2+ + CO2- -> basische, grüne Carbonatsalze wechselnder Zusammensezung. |
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| Source | Own work |
| Author | Tubifex |
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Permission is granted to copy, distribute and/or modify this document under the terms of the GNU Free Documentation License, Version 1.2 or any later version published by the Free Software Foundation; with no Invariant Sections, no Front-Cover Texts, and no Back-Cover Texts. A copy of the license is included in the section entitled GNU Free Documentation License. |
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| Date/Time | Thumbnail | Dimensions | User | Comment | |
|---|---|---|---|---|---|
| current | 17:26, 21 December 2009 | | 1,033 × 1,464 (450 KB) | Tubifex | {{Information |Description={{en|1=Reactions of Nickel(II)-nitrate. From left to right: Pure solution of Nickel(II)-nitrate. You still can see the green color. With (NH4)2S: Ni2+ + S2- -> NiS(s) (The black precipitation is first soluble in acid. After co |
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