Base (chemistry)

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Ammonia and hydrochloric acid from ammonium chloride. This is a neutralization.

A base is a substance that can accept a hydrogen ion (H+) from another substance. A chemical can accept a proton if it has a negative charge, or if the molecule has an electronegative atom like oxygen, nitrogen, or chlorine that is rich in electrons. Like acids, some bases are strong and others are weak. The weak bases are less likely to accept protons, while the strong bases quickly take protons in solution or from other molecules. An acid is a base's "chemical opposite". An acid is a substance that will donate a hydrogen atom to the base.

Bases have a pH greater than 7.0. Weak bases generally have a pH value of 7–9 while strong bases have a pH value of 9–14.

How bases work[change | change source]

Bases can be used to neutralize acids. When a base, often OH, accepts a proton from an acid, it forms a water molecule which is harmless. When all of the acids and bases react to form water molecules and other neutral salts, it is called neutralization. Acids can also be used to neutralize bases.

Every base has a conjugate acid formed by adding a proton to the base. For example, NH3 (ammonia) is a base and its conjugate acid is the ammonium ion, NH4+. A base and its conjugate acid are opposite in strength. Since ammonia is a moderately strong base, ammonium is a considerably weaker acid.

Importance[change | change source]

Bases have these characteristics:

  • Bitter taste (opposed to sour taste of acids)
  • Slimy, or soapy feel on fingers
  • Many bases react with acids and precipitate salts.
  • Strong bases may react violently with acids. An acid spill can be safely neutralised by using a mild base.
  • Bases turn red litmus paper blue
  • Bases are substances that contain metal oxides or hydroxides
  • Bases which are soluble in water form alkalis (soluble bases)

Some common household products are bases. For example, caustic soda and drain cleaner are made from sodium hydroxide, a strong base. Ammonia or an ammonia-based cleaner such as window and glass cleaner, is basic. These stronger bases may cause a skin irritation. Other bases, like cooking ingredients sodium bicarbonate (baking soda) or cream of tartar are basic, but these are not harmful and suitable for cooking.

Gloves should always be worn when handling bases. If skin irritation is encountered, the affected area should be rinsed thoroughly with cold water. If that does not stop the problem, contact medical help as soon as possible.

Strong bases[change | change source]

A strong base is a base that gives off a hydroxide ion, OH–, when put in water. There are eight of them.