Potassium

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Potassium,  19K
Potassium-2.jpg
Potassium pearls (in paraffin oil, ~5 mm each)
General properties
Pronunciation/pəˈtæsiəm/ (pə-TAS-ee-əm)
Appearancesilvery gray
Standard atomic weight (Ar, standard)39.0983(1)[1]
Potassium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Na

K

Rb
argonpotassiumcalcium
Atomic number (Z)19
Groupgroup 1 (alkali metals)
Periodperiod 4
Blocks-block
Element category  alkali metal
Electron configuration[Ar] 4s1
Electrons per shell
2, 8, 8, 1
Physical properties
Phase at STPsolid
Melting point336.7 K ​(63.5 °C, ​146.3 °F)
Boiling point1032 K ​(759 °C, ​1398 °F)
Density (near r.t.)0.862 g/cm3
when liquid (at m.p.)0.828 g/cm3
Critical point2223 K, 16 MPa[2]
Heat of fusion2.33 kJ/mol
Heat of vaporization76.9 kJ/mol
Molar heat capacity29.6 J/(mol·K)
Atomic properties
Oxidation states−1, +1 (a strongly basic oxide)
ElectronegativityPauling scale: 0.82
Ionization energies
  • 1st: 418.8 kJ/mol
  • 2nd: 3052 kJ/mol
  • 3rd: 4420 kJ/mol
  • (more)
Atomic radiusempirical: 227 pm
Covalent radius203±12 pm
Van der Waals radius275 pm
Color lines in a spectral range
Spectral lines of potassium
Other properties
Natural occurrenceprimordial
Crystal structurebody-centered cubic (bcc)
Body-centered cubic crystal structure for potassium
Speed of sound thin rod2000 m/s (at 20 °C)
Thermal expansion83.3 µm/(m·K) (at 25 °C)
Thermal conductivity102.5 W/(m·K)
Electrical resistivity72 nΩ·m (at 20 °C)
Magnetic orderingparamagnetic[3]
Magnetic susceptibility+20.8·10−6 cm3/mol (298 K)[4]
Young's modulus3.53 GPa
Shear modulus1.3 GPa
Bulk modulus3.1 GPa
Mohs hardness0.4
Brinell hardness0.363 MPa
CAS Number7440-09-7
History
Discovery and first isolationHumphry Davy (1807)
Main isotopes of potassium
Iso­tope Abun­dance Half-life (t1/2) Decay mode Pro­duct
39K 93.258% stable
40K 0.012% 1.248×109 y β 40Ca
ε 40Ar
β+ 40Ar
41K 6.730% stable
| references
Potassium metal

Potassium is a chemical element in the periodic table. It has the symbol K. This symbol is taken from the Latin word kalium. Potassium's atomic number is 19. It has 19 protons and electrons. Potassium is not found as an element in nature, because it is so reactive.

Potassium has two stable isotopes, with 20 or 22 neutrons. Its atomic mass is 39.098. The unstable isotope with 21 neutrons is one of the most common radioactive materials.

Properties[change | change source]

Physical properties[change | change source]

Potassium is a soft gray metal. It can be cut easily with a knife. Its melting point is 63 degrees Celsius (145.4 degrees Fahrenheit). It melts at a very low temperature. It is an alkali metal. It is the second lightest metal, after lithium.

Chemical properties[change | change source]

A reaction of potassium metal with water. Hydrogen is liberated. The pink or lilac flame comes from burning potassium vapor. Strongly alkaline potassium hydroxide is formed in solution.[5]

Potassium reacts in many chemical reactions similar to sodium and other alkali metals. It tarnishes in air to produce a whitish oxidized layer on the surface. This is why it is stored in oil. It also reacts very fast with water, which is another reason for its storage in oil. The hydrogen produced during its reaction with water can burst into flames when a large amount of potassium is added to water. Potassium hydroxide is also produced. Potassium also burns in air easily, to make the peroxide or the superoxide.

Chemical compounds[change | change source]

Potassium chloride in a flame

Potassium compounds are only in one oxidation state: +1. Potassium ions are colorless and similar to sodium ions. Potassium chloride can be used as a substitute for table salt. Potassium hydroxide is used in the electrolyte of alkaline cells. Most potassium compounds are nontoxic. If they are toxic, it is because of the anion. Potassium chromate is colored because of the chromate, not the potassium. Potassium chromate is toxic because of the chromate, not the potassium.

Name[change | change source]

The word potassium comes from the word "potash". Potash is a mixture of potassium carbonate and potassium hydroxide that has been used for a very long time. In past centuries potash was made from ashes in pots. It is used to make fertilizer, soap, and glass.

Occurrence[change | change source]

Potassium does not occur in nature because it is too reactive. It is found in minerals, though. It is extracted from them by electrolysis of potassium hydroxide or potassium chloride. The potassium hydroxide or potassium chloride has to be melted at a very high temperature.

Uses[change | change source]

Potassium metal is used to absorb water from solvents. It is also used in some scientific instruments.

Potassium compounds are used in soap, fertilizer, explosives, and matches.

Potassium ions are very important to organisms. That is why fertilizers have potassium compounds in them. The ions send messages from cells to other cells. It helps biological membranes depolarize. This means go from a negative to a positive electrical charge. This is needed for muscles to contract (get shorter and move things.) It is needed for the heart to beat (push blood through blood vessels.) If the potassium level in the blood is too high or too low it can cause death because the heart stops. A few good sources of potassium are bananas, apricots and raisins.

Safety[change | change source]

Potassium metal is very dangerous and can form an explosive coating if it is kept in air. It also reacts violently with water, spewing corrosive liquid. Potassium compounds are not normally dangerous, unless they contain a toxic anion like chromate or chlorate.

Related pages[change | change source]

Other websites[change | change source]

References[change | change source]

  1. Meija, J.; Coplen, T. B.; Berglund, M.; Brand, W.A.; De Bièvre, P.; Gröning, M.; Holden, N.E.; Irrgeher, J. et al. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)". Pure and Applied Chemistry 88 (3): 265-91. doi:10.1515/pac-2015-0305. https://www.degruyter.com/downloadpdf/j/pac.2016.88.issue-3/pac-2015-0305/pac-2015-0305.xml. 
  2. Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, FL: CRC Press. p. 4.122. ISBN 1439855110.
  3. Magnetic susceptibility of the elements and inorganic compounds, in Lide, D. R., ed. (2005). CRC Handbook of Chemistry and Physics (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5.
  4. Weast, Robert (1984). CRC, Handbook of Chemistry and Physics. Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4.
  5. "Potassium". Retrieved 13 October 2010.